肖军安

2019年03月20日 浏览量: 评论(0) 来源: 化学与材料学院 作者: 肖军安

学历、职称:博士、讲师(硕士生导师)

专业方向:催化不对称合成

联系方式:jaxiao@csu.edu.cn

 

教育与研究经历

2008.9-2012.7 :湖南科技学院化学专业,获理学学士学位

2012.9-2017.6 :中南大学有机化学专业,获理学博士学位,导师:阳华 教授

 

课题组主要从事有机小分子催化剂及高效手性配体的设计合成以及新型有机硒试剂的开发与应用注重于开发新颖绿色的有机合成方法学并应用于复杂环状分子的高效合成。近年来在三元张力环开环反应光氧化还原催化有机硒化学及机械力化学等领域取得了一定进展,以第一作者或通讯作者身份在Chemcal Communications、Organic Chemistry Frontiers、The Journal of Organic Chemistry等杂志发表高水平SCI论文10余篇合作论文30余篇,申请专利3项。目前主持国家自然科学基金1项,广西青年科学基金1项,广西青年创新人才专项项目1项,广西教育厅项目1项,课题研究经费累计80余万元。

教学情况

  主讲本科生专业基础课《有机化学》和专业选修课《有机合成》。指导本科生累计获得国家级大学生创新创业项目1项,自治区级大学生创新创业项目3项;指导本科生获得广西高校大学生化学化工类学术论文竞赛二等奖1项,三等奖1项。

承担项目与课题

(1) 国家自然科学基金地区基金项目,““边臂”强化三蝶烯膦配体的设计合成及其在催化不对称构建氧化吲哚螺环中的应用”,项目编号:21861008,40万,主持在研。

(2) 广西科技厅青年创新人才专项,“有机硒试剂的设计、合成及其在硒化反应中的应用”,项目合同编号:桂科AD19245049,10万,主持在研。

(3) 广西自然科学基金青年基金项目,“金属-有机双功能催化剂的功能导向合成与不对称催化应用”,项目编号:2018GXNSFBA138037,10万,主持在研。

(4) 广西高校中青年教师基础能力提升计划项目,“新型胍类多氢键有机催化剂的合成及其不对称催化应用”,项目编号:2018KY0364,3万,主持在研。

(5) 广西师范学院博士科研启动经费,18万。

 主要学术论文(* 通讯作者)

2020年

(1) Jianguo Cui, Meizhen Wei, Liping Pang, Jun-An Xiao(*), Chunfang Gan, Jiali Guo, Chuanfang Xie, Qiming Zhu, Yanmin Huang(*), Oxidative umpolung selenocyanation of ketones and arenes: An efficient protocol to the synthesis of selenocyanates, Tetrahedron, 2020, ASAP, DOI: https://doi.org/10.1016/j.tet.2020. 130978.

2019年

(1) Jun-An Xiao,(*) Li, Y.-C., Cheng, X.-L., Chen, W., Cui, J.-G.,Huang, Y.-M., Huang, J., Xiao, Q., Su, W.,* Yang, H.,* Selenocyanobenziodoxolone: a practical electrophilic selenocyanation reagent and its application for solid-state synthesis of α-carbonyl selenocyanates. Org. Chem. Front. 2019, 6, (12), 1967-1971.

(2) Jun-An Xiao, Yu-Chun Li, Zhi-Jin Luo, Xiu-Liang Cheng, Zhi-Xiong Deng, Wen-Qiang Chen, Wei Su(*), Hua Yang. Construction of Bispirooxindole Heterocycles via Palladium-Catalyzed Ring-Opening Formal [3 + 2]-Cycloaddition of Spirovinylcyclopropyl Oxindole and 3-Oxindole Derivatives. J. Org. Chem., 2019, 84(4): 2297-2306.

(3) Jun-An Xiao, Xiu-Liang Cheng, Yu-Chun Li, Yi-Miao He, Jin-Lian Li, Zhi-Ping Liu, Peng-Ju Xia, Wei Su(*), Hua Yang(*). Palladium-catalysed ring-opening [3 + 2]-annulation of spirovinylcyclopropyl oxindole to diastereoselectively access spirooxindoles. Org. Biomol. Chem., 2019, 17(1): 103-107.

(4) Liu, Z.-P., Li, J.-L., Cheng, X.-L., Cui, J.-G., Huang, Y.-M., Gan, C.-F., Su, W., Jun-An Xiao,(*) Visible-Light-Induced Ring-Opening of Hydrogenolysis Spirocyclopropyl Oxindoles Through Photoredox Catalysis. Eur. J. Org. Chem. 2019, 2019, (25), 4085-4088.

2017年

(1) Wen, S.-S.,# Zhou, Z.-F., # Jun-An Xiao, # Li, J., Xiang, H.-Y., Yang, H., (*) Facile oxidative cyclization to access C2-quaternary 2-hydroxy-indolin-3-ones: synthetic studies towards matemone. New J. Chem. 2017, 41, (20), 11503-11506.

2017年以前

(1) Jun-An Xiao, Peng-Ju Xia, Xing-Yu Zhang, Xiao-Qing Chen(*), Guang-Chuan Ou, Hua Yang(*), Amide-assisted intramolecular [3+2] annulation of cyclopropane ring-opening: a facile anddiastereoselective access to the tricyclic core of (±)-scandine, Chemical Communications, 2016, 52(10): 2177~2180   

(2) Jun-An Xiao, Jie Li, Peng-Ju Xia, Zhao-Fang Zhou, Zhao-Xu Deng, Hao-Yue Xiang(*), Xiao-Qing Chen, Hua Yang(*), Diastereoselective Intramolecular [3 + 2]-Annulation of Donor-Acceptor Cyclopropane with Imine-Assembling Hexahydropyrrolo [3,2-c]quinolinone Scaffolds, Journal of Organic Chemistry, 2016, 81(22): 11185~11194   

(3) Jun-An Xiao, Hong-Gang Zhang, Shan Liang, Ji-Wei Ren, Hua Yang(*), Xiao-Qing Chen(*), Synthesis of Pyrrolo(spiro-[2.3']-oxindole)-spiro-[4.3'']-oxindole via 1,3-Dipolar Cycloaddition of Azomethine Ylides with 3-Acetonylideneoxindole, Journal of Organic Chemistry, 2013, 78(22): 11577~11583  

(4) Jun-An Xiao(#), Qi Liu(#), Ji-Wei Ren, Jian Liu, Rich G Carter, Xiao-Qing Chen(*), Hua Yang(*), Highly Enantioselective Construction of Polycyclic Spirooxindoles by Organocatalytic1,3-Dipolar Cycloaddition of 2-Cyclohexenone Catalyzed by Proline-Sulfonamide, European Journal of Organic Chemistry, 2014, 2014(26): 5700~5704   

(5) Jun-An Xiao, Chao-Ming Wang, Jing Wang, Guang-Chuan Ou, Xing-Yu Zhang, Hua Yang(*), Highly stereoselective synthesis of novel spiroimidazolidinones directed by pyridineprolinamide, Tetrahedron, 2015, 2015(1): 805~812